Effect of Reduced Graphite Oxide as Substrate for Zinc Oxide to Hydrogen Sulfide Adsorption 


Vol. 19,  No. 3, pp. 300-305, Sep.  2013
10.7464/ksct.2013.19.3.300


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  Abstract

Zinc oxide (ZnO) and reduced graphite oxide (rGO) composites were synthesized and tested as adsorbents for the hydrogen sulfide (H2S) adsorption at mid-to-high (300 to 500 ℃) temperatures. In order to investigate the critical roles of oxygen containing functional groups, such as hydroxyl, epoxy and carboxyl groups, attached on rGO surface for the H2S adsorption, various characterization methods (TGA, XRD, FT-IR, SEM and XPS) were conducted. For the reduction process for graphite oxide (GO) to rGO, a microwave irradiation method was used, and it provided a mild reduction environment which can remain substantial amount of oxygen functional groups on rGO surface. Those functional groups were anchoring and holding nano-sized ZnO onto the 2D rGO surface; and it prevented the aggregation effect on the ZnO particles even at high temperature ranges. Therefore, the H2S adsorption capacity had been increased about 3.5 times than the pure ZnO.

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  Cite this article

[IEEE Style]

J. NR, S. HS, P. MG, K. SJ, R. HJ, Y. KB, "Effect of Reduced Graphite Oxide as Substrate for Zinc Oxide to Hydrogen Sulfide Adsorption," Clean Technology, vol. 19, no. 3, pp. 300-305, 2013. DOI: 10.7464/ksct.2013.19.3.300.

[ACM Style]

Jeon NR, Song HS, Park MG, Kwon SJ, Ryu HJ, and Yi KB. 2013. Effect of Reduced Graphite Oxide as Substrate for Zinc Oxide to Hydrogen Sulfide Adsorption. Clean Technology, 19, 3, (2013), 300-305. DOI: 10.7464/ksct.2013.19.3.300.

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