Removal of SO2 over Binary Nb/Fe Mixed Oxide Catalysts 


Vol. 12,  No. 2, pp. 87-94, Jun.  2006


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  Abstract

The reduction of SO2 to elemental sulfur by CO over a series of iron niobate with nominal Nb/Fe atomic ratios of 1/0, 10/1, 5/1, 1/1, 1/5, 1/10 and 0/1 was studied with a flow fixed-bed reactor. Strong synergistic phenomena in catalytic activity and selectivity were observed for the iron niobate catalysts, and the best catalytic performance was observed for the catalyst with Fe/Nb atomic ratio of 1/1. The active phase of the activated iron niobate catalysts was identified to be FeS2 using XRD and XPS. Selective reduction of SO2 by CO was followed by the COS intermediate mechanism.

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  Cite this article

[IEEE Style]

C. JK, L. SH, P. DW, W. HC, "Removal of SO2 over Binary Nb/Fe Mixed Oxide Catalysts," Clean Technology, vol. 12, no. 2, pp. 87-94, 2006. DOI: .

[ACM Style]

Chung JK, Lee SH, Park DW, and Woo HC. 2006. Removal of SO2 over Binary Nb/Fe Mixed Oxide Catalysts. Clean Technology, 12, 2, (2006), 87-94. DOI: .