Modelling Phase Equilibria of Binary Mixtures for the Direct Synthesis of dimethyl carbonate from CO2 


Vol. 11,  No. 4, pp. 165-170, Dec.  2005


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  Abstract

The aim of this study is to provide vapor-liquid equilibrium (VLE) information for the study of process which directly synthesize dimethyl carbonate (DMC) from CO2. For this study we collected some necessary VLE systems data of Methanol-Water, Methanol-DMC, CO2-DMC, CO2-Methanol, CO2-Methanol, and performed VLE calculation with Peng-Robinson equation of state, Wong-Sandler mixing rules that widely used in chemical industry. These calculation results relatively agreed with VLE data well. Optimized Parameters of EoS given through this calculation will be used as some valuable information for fundmental study, process development and process optimization of DMC direct synthesis.

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  Cite this article

[IEEE Style]

I. J, L. G, A. J, K. H, "Modelling Phase Equilibria of Binary Mixtures for the Direct Synthesis of dimethyl carbonate from CO2," Clean Technology, vol. 11, no. 4, pp. 165-170, 2005. DOI: .

[ACM Style]

Im J, Lee G, An J, and Kim H. 2005. Modelling Phase Equilibria of Binary Mixtures for the Direct Synthesis of dimethyl carbonate from CO2. Clean Technology, 11, 4, (2005), 165-170. DOI: .

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pISSN : 1598 - 9712
eISSN : 2288 - 0690

한국연구재단 등재학술지