Adsorption Characteristics of Methane and Carbon Dioxide in Zeolite with Flexible Framework 


Vol. 30,  No. 3, pp. 248-257, Sep.  2024
10.7464/ksct.2024.30.3.248


PDF
  Abstract

Carbon dioxide is an undesired component of biogas and landfill gas. As a result, it needs to be removed from these mixtures in order to increase their heating value and reduce corrosion during treatment. Zeolites are a class of microporous materials that can be used as adsorbents for the separation of carbon dioxide from gas mixtures. In this work, the pure gas adsorption isotherms of methane and carbon dioxide and the selectivity of their mixture onto LTA-4A, FAU-13X and FAU-NaY adsorbents at temperatures of 273, 298 and 323 K and pressures up to 30 bars were calculated by the Monte Carlo method. Also, the influence of a flexible framework in a set of zeolites on the separation of methane and carbon dioxide was studied. Carbon dioxide adsorption onto the zeolites used in this work was more favorable than methane adsorption. The FAU-13X adsorbent had the highest adsorption capacity among the studied adsorbents. However, the selectivity of carbon dioxide over methane for LTA-4A was the highest. The adsorption capacities of a rigid framework were higher than those of a flexible framework. The influence of the framework flexibility in FAU on adsorption capacity was small. In contrast, its influence on selectivity seemed to be much larger.

  Statistics
Cumulative Counts from November, 2022
Multiple requests among the same browser session are counted as one view. If you mouse over a chart, the values of data points will be shown.


  Cite this article

[IEEE Style]

Y. G. Seo, "Adsorption Characteristics of Methane and Carbon Dioxide in Zeolite with Flexible Framework," Clean Technology, vol. 30, no. 3, pp. 248-257, 2024. DOI: 10.7464/ksct.2024.30.3.248.

[ACM Style]

Yang Gon Seo. 2024. Adsorption Characteristics of Methane and Carbon Dioxide in Zeolite with Flexible Framework. Clean Technology, 30, 3, (2024), 248-257. DOI: 10.7464/ksct.2024.30.3.248.

Search
(IN TITLE, AUTHOR, ABSTRACT,KEYWORDS)

Advanced Search ▼

POPULAR KEYWORDS
(TOP 10 KEYWORDS)

Recent Publications
(LAST 3 YEARS)

pISSN : 1598 - 9712
eISSN : 2288 - 0690

한국연구재단 등재학술지